Showing posts with label acids. Show all posts
Showing posts with label acids. Show all posts

Wednesday, April 30, 2008

pH

pH is the measure of the acidity or basicity of a solution. It is formally a measure of the activity of dissolved hydrogen ions (H+), but for very dilute solutions, the molarity (molar concentration) of H+ may be used as a substitute with little loss of accuracy.

In pure water at 25°C, the concentration of H+ equals the concentration of hydroxide ions (OH-). This is defined as "neutral" and corresponds to a pH level of 7.0. Solutions in which the concentration of H+ exceeds that of OH- have a pH value lower than 7.0 and are known as acids. Solutions in which OH- exceeds H+ have a pH value greater than 7.0 and are known as bases.

The concept of pH was first introduced by Danish chemist S. P. L. Sørensen at the Carlsberg Laboratory in 1909

Base

In chemistry, a base is most commonly thought of as a substance that can accept protons. This refers to the Brønsted-Lowry theory of acids and bases. Alternate definitions of bases include electron pair donors (Lewis), as sources of hydroxide anions (Arrhenius) and can be (commonly) thought of as any chemical compound that, when dissolved in water, gives a solution with a pH higher than 7.0. Examples of simple bases are sodium hydroxide and ammonia.

Acid

An acid (often represented by the generic formula HA [H+A-]) is traditionally considered any chemical compound that, when dissolved in water, gives a solution with a hydrogen ion activity greater than in pure water, i.e. a pH less than 7.0. That approximates the modern definition of Johannes Nicolaus Brønsted and Martin Lowry, who independently defined an acid as a compound which donates a hydrogen ion (H+) to another compound (called a base). Common examples include acetic acid (in vinegar) and sulfuric acid (used in car batteries). Acid/base systems are different from redox reactions in that there is no change in oxidation state.